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Title: "Virtual Injector" Flow Tube Method for Measuring Relative Rates Kinetics of Gas-Phase and Aerosol Species
Journal: J. Phys. Chem. A
Volume: 116
Page(s): 6664 - 6674
Year: 2012
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2012REN/SMI6664-6674
Reaction:
CH3CH2CH2CHO + ·OH → Products
Reaction order:
2
Reference reaction:
Naphthalene + ·OH → Products
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
2.41x10-11 [±3.9x10-12 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
The technique of "virtual injector" with laser photolysis at 10 Hz and product detection by a chemical ionization mass spectrometer was used.
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