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Home ©NIST, 2013 Accessibility information |
Title: High temperature measurements for the rate constants of C1-C-4 aldehydes with OH in a shock tube
Journal: Proc. Combust. Inst.
Volume: 35
Page(s): 473 - 480
Year: 2015
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2015WAN/DAV473-480
Reaction:
CH3CH2CH2CHO + ·OH → Products
Reaction order:
2
Temperature:
1013 - 1315
K
Pressure: 0.92 - 2.20 bar
Rate expression:
1.11x10-12 [cm3/molecule s] (T/298 K)2.06 e5471 [J/mole]/RT
Uncertainty:
1.25
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
The uncertainty of the expression is estimated at 25%.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1013 | 2.65E-11 |
| 1025 | 2.69E-11 |
| 1050 | 2.79E-11 |
| 1075 | 2.88E-11 |
| 1100 | 2.98E-11 |
| 1125 | 3.08E-11 |
| 1150 | 3.18E-11 |
| 1175 | 3.29E-11 |
| 1200 | 3.39E-11 |
| 1225 | 3.50E-11 |
| 1250 | 3.61E-11 |
| 1275 | 3.72E-11 |
| 1300 | 3.84E-11 |
| 1315 | 3.91E-11 |