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©NIST, 2013
Accessibility information
Author(s):   Wang, S. K.; Davidson, D. F.; Hanson, R. K.
Title:   High temperature measurements for the rate constants of C1-C-4 aldehydes with OH in a shock tube
Journal:   Proc. Combust. Inst.
Volume:   35
Page(s):   473 - 480
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015WAN/DAV473-480

Reaction:   CH3CH2CH2CHO + ·OH → Products
Reaction order:   2
Temperature:   1013 - 1315 K
Pressure:  0.92 - 2.20 bar
Rate expression:   1.11x10-12 [cm3/molecule s] (T/298 K)2.06 e5471 [J/mole]/RT
Uncertainty:   1.25
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   The uncertainty of the expression is estimated at 25%.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1013 2.65E-11
1025 2.69E-11
1050 2.79E-11
1075 2.88E-11
1100 2.98E-11
1125 3.08E-11
1150 3.18E-11
1175 3.29E-11
1200 3.39E-11
1225 3.50E-11
1250 3.61E-11
1275 3.72E-11
1300 3.84E-11
1315 3.91E-11