Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: High temperature measurements for the rate constants of C1-C-4 aldehydes with OH in a shock tube
Journal: Proc. Combust. Inst.
Volume: 35
Page(s): 473 - 480
Year: 2015
Book Title: ''
Editor: ''
Publisher: ''
Publisher address: ''
Comments: ''
Reference type: Journal article
Squib: 2015WAN/DAV473-480
Reaction:
CH3CH2CH2CHO + ·OH → Products
Reaction order:
2
Temperature:
258 - 1315
K
Rate expression:
no rate data available
Category: Experiment
Data type:
Experimental value and limited review
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
Experimental data obtained in this work were combined with lower temperature literature data to obtain the temperature dependence of the rate constant over a wide temperature range. The temperature dependence of the rate constant is expressed as k(T) = 1.19×1014 exp(-2343 K/T) + 2.90×1012 exp(+481 K/T) cm3 mol-1 s-1. The uncertainty of the expression is estimated at 28%.
View full bibliographic record.