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Author(s):   Mashino, M.; Ninomiya, Y.; Kawasaki, M.; Wallington, T. J.; Hurley, M. D.
Title:   Atmospheric Chemistry of CF3CF=CF2: Kinetics and Mechanism of Its Reactions with OH Radicals, Cl Atoms, and Ozone
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   7255 - 7260
Year:   2000
Reference type:   Journal article
Squib:   2000MAS/NIN7255-7260

Reaction:   CF3CF=CF2 + ·Cl → Products
Reaction order:   2
Reference reaction:   C2H4 + ·Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  1.01 bar
Rate expression:   2.9x10-1±2.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The ratio of (0.29 +/- 0.02) was measured.The rate constant k(Cl + C2H4) = 9.29E-11 was accepted for the reference reaction to calculate the reported value. Photolysis of Cl in 760 Torr O2/N2 as a source of Cl atoms in a 140 L Pyrex reactor coupled with FTIR spectrometer at T= 296 ?2 K

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