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Accessibility information
Author(s):   Harding, L.B.; Klippenstein, S.J.; Miller, J.A.
Title:   Kinetics of CH+N2 revisited with multireference methods
Journal:   J. Phys. Chem. A
Volume:   112
Page(s):   522 - 532
Year:   2008
Reference type:   Journal article
Squib:   2008HAR/KLI522-532

Reaction:   ·CH + N2NCN +
Reaction order:   2
Temperature:   400 - 3000 K
Rate expression:   4.06x10-13 [cm3/molecule s] (T/298 K)1.12 e-73325 [J/mole]/RT
Category:  Theory
Data type:   Ab initio

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
400 1.50E-22
500 1.59E-20
600 3.68E-19
700 3.57E-18
800 2.01E-17
900 7.79E-17
1000 2.34E-16
1100 5.80E-16
1200 1.25E-15
1300 2.40E-15
1400 4.23E-15
1500 6.96E-15
1600 1.08E-14
1700 1.60E-14
1800 2.28E-14
1900 3.13E-14
2000 4.18E-14
2100 5.45E-14
2200 6.95E-14
2300 8.69E-14
2400 1.07E-13
2500 1.30E-13
2600 1.55E-13
2700 1.84E-13
2800 2.15E-13
2900 2.49E-13
3000 2.87E-13