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Title: Reaction of Hydrogen Atoms with Diethyldisulfide and Ethylmethyldisulfide
Journal: Int. J. Chem. Kinet.
Volume: 13
Page(s):
Year: 1981
Reference type: Journal article
Squib: 1981EKW/SAF799
Reaction:
(C2H5S)2 + CH3CH2S → Other Products + C2H5SH
Reaction order:
2
Reference reaction:
CH3CH2S + CH3CH2S → Products
Temperature:
298 - 418
K
Pressure: 0.77 - 0.80 bar
Rate expression:
3.49x10-12 [cm3/molecule s] e-15132 [J/mole]/RT
Bath gas:
H2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Sensitized photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 7.76E-15 |
| 300 | 8.09E-15 |
| 325 | 1.29E-14 |
| 350 | 1.92E-14 |
| 375 | 2.72E-14 |
| 400 | 3.68E-14 |
| 418 | 4.48E-14 |