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Title: A kinetic study of the reaction of chlorine atoms with CF3CHCl2, CF3CH2F, CFCl2CH3, CF2ClCH3, CHF2CH3, CH3D, CH2D2, CHD3, CD4, and CD3Cl at 295 ± 2 K
Journal: Chem. Phys. Lett.
Volume: 189
Page(s): 437 - 442
Year: 1992
Reference type: Journal article
Squib: 1992WAL/HUR437-442
Reaction:
CH2D2 + ·Cl → Products
Reaction order:
2
Reference reaction:
CH4 + ·Cl → ·CH3 + HCl
Temperature:
295
K
Pressure: 0.93 bar
Rate expression:
4.57x10-14 [±2.32x10-15 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
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