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Author(s):   Wallington, T.J.; Hurley, M.D.
Title:   A kinetic study of the reaction of chlorine atoms with CF3CHCl2, CF3CH2F, CFCl2CH3, CF2ClCH3, CHF2CH3, CH3D, CH2D2, CHD3, CD4, and CD3Cl at 295 ± 2 K
Journal:   Chem. Phys. Lett.
Volume:   189
Page(s):   437 - 442
Year:   1992
Reference type:   Journal article
Squib:   1992WAL/HUR437-442

Reaction:   CH2D2 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Temperature:   295 K
Pressure:  0.93 bar
Rate expression:   4.57x10-14 [±2.32x10-15 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

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