Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Boone, G.D.; Agyin, F.; Robichaud, D.J.; Tao, F.-M.; Hewitt, S.A.
Title:   Rate Constants for the Reactions of Chlorine Atoms with Deuterated Methanes: Experiment and Theory
Journal:   J. Phys. Chem. A
Volume:   105
Page(s):   1456 - 1464
Year:   2001
Reference type:   Journal article
Squib:   2001BOO/AGY1456-1464

Reaction:   CH2D2 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   4.2x10-14±5.0x10-15
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Reaction rates were measured in N2 relative to Cl + CH4, where kref (Cl+CH4) = 1 x 10-13 cm3 molecule s-1 is used to derive k.

View full bibliographic record.