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Title: Rate Constants for the Reactions of Chlorine Atoms with Deuterated Methanes: Experiment and Theory
Journal: J. Phys. Chem. A
Volume: 105
Page(s): 1456 - 1464
Year: 2001
Reference type: Journal article
Squib: 2001BOO/AGY1456-1464
Reaction:
CH2D2 + ·Cl → Products
Reaction order:
2
Reference reaction:
(13)CO + ·Cl → (13)CO
Reference reaction order:
3
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
3.4x10-14 [±5.0x10-15 molecule/cm3]
Bath gas:
air
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
Comments:
Reaction rates were measured in synthetic air relative to Cl + 13CO + M -> Cl13CO + M, where kref (Cl+CH4) = 3.2 x 10-14 cm3 molecule s-1 is used to derive k.
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