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Author(s):   Demissy, M.; Lesclaux, R.
Title:   Kinetics of Hydrogen Abstraction by NH2 Radicals from Alkanes in the Gas Phase. A Flash Photolysis-Laser Resonance Absorption Study
Journal:   J. Am. Chem. Soc.
Volume:   102
Year:   1980
Reference type:   Journal article
Squib:   1980DEM/LES2897

Reaction:   C2H6 + ·NH2·C2H5 + NH3
Reaction order:   2
Temperature:   300 - 520 K
Pressure:  5.33E-4 - 0.67 bar
Rate expression:   6.14x10-13 [cm3/molecule s] e-29932 [±1197 J/mole]/RT
Bath gas:   C2H6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 3.77E-18
325 9.50E-18
350 2.10E-17
375 4.16E-17
400 7.58E-17
425 1.29E-16
450 2.06E-16
475 3.14E-16
500 4.59E-16
520 6.05E-16