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Title: Kinetics of Hydrogen Abstraction by NH2 Radicals from Alkanes in the Gas Phase. A Flash Photolysis-Laser Resonance Absorption Study
Journal: J. Am. Chem. Soc.
Volume: 102
Page(s):
Year: 1980
Reference type: Journal article
Squib: 1980DEM/LES2897
Reaction:
1-C4H10 + ·NH2 → Other Products + NH3
Reaction order:
2
Temperature:
300 - 520
K
Pressure: 5.33E-4 - 0.53 bar
Rate expression:
1.16x10-12 [cm3/molecule s] e-25525 [±1023 J/mole]/RT
Bath gas:
1-C4H10
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 300 | 4.18E-17 |
| 325 | 9.18E-17 |
| 350 | 1.80E-16 |
| 375 | 3.24E-16 |
| 400 | 5.40E-16 |
| 425 | 8.48E-16 |
| 450 | 1.27E-15 |
| 475 | 1.81E-15 |
| 500 | 2.50E-15 |
| 520 | 3.17E-15 |