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Title: Kinetics of nitric oxide catalyzed decomposition of nitryl chloride and its related nitrogen isotope exchange reactions
Journal: J. Phys. Chem.
Volume: 78
Page(s): 2073 - 2076
Year: 1974
Reference type: Journal article
Squib: 1974WIL/DOD2073-2076
Reaction:
NO + ClNO2 → NOCl + NO2
Reaction order:
2
Temperature:
265 - 323
K
Pressure: 0.63 bar
Rate expression:
2.34x10-12 [cm3/molecule s] e-28851 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 265 | 4.82E-18 |
| 275 | 7.75E-18 |
| 300 | 2.22E-17 |
| 323 | 5.06E-17 |