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Author(s):   Brooks, C.T.
Title:   Gas-phase high-pressure decomposition of isobutane in the presence of hydrogen
Journal:   Trans. Faraday Soc.
Volume:   62
Page(s):   935 - 944
Year:   1966
Reference type:   Journal article
Squib:   1966BRO935-944

Reaction:   iso-C4H102-C3H7 + ·CH3
Reaction order:   1
Temperature:   823 - 853 K
Pressure:  20.26 - 70.93 bar
Rate expression:   7.94x1018 [s-1] e-335073 [±10061 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
823 4.30E-3
825 4.84E-3
850 2.04E-2
853 2.41E-2