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Author(s):   Golden, D.M.; Alfassi, Z.B.; Beadle, P.C.
Title:   Very Low-Pressure Pyrolysis (VLPP) of Alkanes: n-Butane, 2,3-Dimethylbutane, 2,2',3,3'-Tetramethylbutane, and Isobutane
Journal:   Int. J. Chem. Kinet.
Volume:   6
Year:   1974
Reference type:   Journal article
Squib:   1974GOL/ALF359

Reaction:   iso-C4H102-C3H7 + ·CH3
Reaction order:   1
Temperature:   1100 - 1280 K
Rate expression:   2.51x1016 [s-1] e-346713 [J/mole]/RT
Bath gas:   iso-C4H10
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 8.63E-1
1125 2.00E0
1150 4.49E0
1175 9.70E0
1200 2.03E1
1225 4.13E1
1250 8.16E1
1275 1.57E2
1280 1.78E2