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Author(s):   Pratt, G.L.; Rogers, D.
Title:   Wall-less Reactor Studies. Part 4. - Isobutane Pyrolysis
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   76
Year:   1980
Reference type:   Journal article
Squib:   1980PRA/ROG1694

Reaction:   iso-C4H102-C3H7 + ·CH3
Reaction order:   1
Temperature:   970 - 1030 K
Pressure:  0.80 bar
Rate expression:   8.39x1015 [s-1] e-357522 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
970 4.69E-4
975 5.89E-4
1000 1.77E-3
1025 5.06E-3
1030 6.21E-3