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Author(s):   Koike, T.; Morinaga, K.
Title:   UV Absorption Studies of the Pyrolysis of Isobutane in Shock Waves
Journal:   Bull. Chem. Soc. Jpn.
Volume:   55
Page(s):  
Year:   1982
Reference type:   Journal article
Squib:   1982KOI/MOR690

Reaction:   iso-C4H102-C3H7 + ·CH3
Reaction order:   1
Temperature:   1300 - 1800 K
Pressure:  0.51 bar
Rate expression:   6.31x1012 [s-1] e-254423 [±20370 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 3.78E2
1350 9.04E2
1400 2.03E3
1450 4.31E3
1500 8.72E3
1550 1.68E4
1600 3.12E4
1650 5.57E4
1700 9.61E4
1750 1.61E5
1800 2.61E5