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Author(s):   Tsang, W.
Title:   Rate constants for the decomposition and formation of simple alkanes over extended temperature and pressure ranges
Journal:   Combust. Flame
Volume:   78
Page(s):   71 - 86
Year:   1989
Reference type:   Journal article
Squib:   1989TSA71-86

Reaction:   iso-C4H102-C3H7 + ·CH3
Reaction order:   1
Temperature:   713 - 2000 K
Rate expression:   3.84x1019 [s-1] (T/298 K)-2.61 e-378308 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
713 7.60E-10
800 5.81E-7
900 2.37E-4
1000 2.83E-2
1100 1.38E0
1200 3.45E1
1300 5.18E2
1400 5.20E3
1500 3.79E4
1600 2.13E5
1700 9.70E5
1800 3.70E6
1900 1.21E7
2000 3.52E7