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Author(s):   Chen, W.-Y.; Matsui, H.; Wang, N.-S.
Title:   A comparative study on the production yield of H atom in the thermal decomposition of i-C4H10 and n-C4H10: Examination of the contribution of the roaming radical channels
Journal:   Chem. Phys. Lett.
Volume:   691
Page(s):   56 - 60
Year:   2018
Reference type:   Journal article
Squib:   2018CHE/MAT56-60

Reaction:   iso-C4H102-C3H7 + ·CH3
Reaction order:   1
Reference reaction:   iso-C4H10 → Products
Reference reaction order:   1
Temperature:   1470 - 1800 K
Pressure:  1.00 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   The branching fraction is expressed as (0.064 ± 0.149)(10-3T/K) + (0.06 ± 0.23).

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