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Author(s):   Wallington, T.J.; Hurley, M.D.; Nielsen, O.J.; Sehested, J.
Title:   Atmospheric chemistry of CF3COx radicals: fate of CF3CO radicals, the UV absorption spectrum of CF3C(O)O2 radicals, and kinetics of the reaction CF3C(O)O2 + NO →’ CF3C(O)O + NO2
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   5686 - 5694
Year:   1994
Reference type:   Journal article
Squib:   1994WAL/HUR5686-5694

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994WAL/HUR5686-5694   CF3CHO + ·FCF3C(O)· + HF  296   2.31E-11              2
  1994WAL/HUR5686-5694   CF3C(O)·CO + ·CF3  296   1.20E05              1
  1994WAL/HUR5686-5694   CF3C(O)· + O2 → CF3C(O)OO(·)  296   7.31E-13              2
  1994WAL/HUR5686-5694   CF3C(O)· + O2 → CF3C(O)OO(·)  296   7.41E-18              2
  Reference reaction:  CF3C(O)·CO + ·CF3 1
  1994WAL/HUR5686-5694   NO + CF3C(O)OO(·) → NO2 + CF3C(O)O  296   >9.90E-12              2

Search returned 5 records.