Author(s):   Wallington, T.J.; Hurley, M.D.; Nielsen, O.J.; Sehested, J.
Title:   Atmospheric chemistry of CF₃CO_x radicals: fate of CF₃CO radicals, the UV absorption spectrum of CF₃C(O)O₂ radicals, and kinetics of the reaction CF₃C(O)O₂ + NO → CF₃C(O)O + NO₂
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   5686 - 5694
Year:   1994
Reference type:   Journal article
Squib:   1994WAL/HUR5686-5694

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1994WAL/HUR5686-5694	CF₃CHO + ·F → CF₃C(O)· + HF	296	2.31E-11		2
1994WAL/HUR5686-5694	CF₃C(O)· → CO + ·CF₃	296	1.20E05		1
1994WAL/HUR5686-5694	CF₃C(O)· + O₂ → CF₃C(O)OO(·)	296	7.31E-13		2
1994WAL/HUR5686-5694	CF₃C(O)· + O₂ → CF₃C(O)OO(·)	296	7.41E-18		2
Reference reaction: CF₃C(O)· → CO + ·CF₃				1
1994WAL/HUR5686-5694	NO + CF₃C(O)OO(·) → NO₂ + CF₃C(O)O	296	>9.90E-12		2

Search returned 5 records.