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Author(s):   Wallington, T.J.; Hurley, M.D.; Nielsen, O.J.; Sehested, J.
Title:   Atmospheric chemistry of CF3COx radicals: fate of CF3CO radicals, the UV absorption spectrum of CF3C(O)O2 radicals, and kinetics of the reaction CF3C(O)O2 + NO →’ CF3C(O)O + NO2
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   5686 - 5694
Year:   1994
Reference type:   Journal article
Squib:   1994WAL/HUR5686-5694

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1994WAL/HUR5686-5694   CF3CHO + ·FCF3C(O)· + HF  296   2.31E-11              2
  1994WAL/HUR5686-5694   CF3C(O)·CO + ·CF3  296   1.20E05              1
  1994WAL/HUR5686-5694   CF3C(O)· + O2 → CF3C(O)OO(·)  296   7.31E-13              2
  1994WAL/HUR5686-5694   CF3C(O)· + O2 → CF3C(O)OO(·)  296   7.41E-18              2
  Reference reaction:  CF3C(O)·CO + ·CF3 1
  1994WAL/HUR5686-5694   NO + CF3C(O)OO(·) → NO2 + CF3C(O)O  296   >9.90E-12              2

Search returned 5 records.