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Title: Photochemistry of the Gaseous Hydrogen Peroxide-Carbon Monoxide System. II: Rate Constants for Hydroxyl Radical Reactions with Hydrocarbons and for Hydrogen Atom Reactions with Hydrogen Peroxide
Journal: J. Photochem.
Volume: 3
Page(s):
Year: 1974
Reference type: Journal article
Squib: 1974GOR/VOL115
Reaction:
Cyclobutane + ·OH → Cyclobutyl + H2O
Reaction order:
2
Reference reaction:
CO + ·OH → CO2 + H·
Temperature:
298
K
Pressure: 3.73E-3 - 4.25E-2 bar
Rate expression:
1.2x10-12 [±2.99x10-13 cm3/molecule s]
Bath gas:
CO
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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