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Author(s):   Maricq, M.M.; Szente, J.J.; Khitrov, G.A.; Francisco, J.S.
Title:   The CF3C(O)O2 radical. Its UV spectrum, self-reaction kinetics, and reaction with NO
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   4514 - 4520
Year:   1996
Reference type:   Journal article
Squib:   1996MAR/SZE4514-4520

Reaction:   CF3O2 + CF3C(O)OO(·) → O2 + CF3C(O)O + CF3O
Reaction order:   2
Temperature:   210 - 295 K
Pressure:  0.20 - 0.23 bar
Rate expression:   2.01x10-12 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:   O2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

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