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Title: The CF3C(O)O2 radical. Its UV spectrum, self-reaction kinetics, and reaction with NO
Journal: J. Phys. Chem.
Volume: 100
Page(s): 4514 - 4520
Year: 1996
Reference type: Journal article
Squib: 1996MAR/SZE4514-4520
Reaction:
CF3O2 + CF3C(O)OO(·) → O2 + CF3C(O)O + CF3O
Reaction order:
2
Temperature:
210 - 295
K
Pressure: 0.20 - 0.23 bar
Rate expression:
2.01x10-12 [cm3/molecule s]
Rate constant is an upper limit.
Bath gas:
O2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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