Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Tsang, W.; Hampson, R.F.
Title:   Chemical kinetic data base for combustion chemistry. Part I. Methane and related compounds
Journal:   J. Phys. Chem. Ref. Data
Volume:   15
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986TSA/HAM1087

Reaction:   CH4·CH3 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   3.72x1015 [s-1] e-434015 [J/mole]/RT
Uncertainty:   1.5
Bath gas:   N2
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.01E-60
400 7.85E-42
500 1.70E-30
600 6.12E-23
700 1.53E-17
800 1.71E-13
900 2.41E-10
1000 7.95E-8
1100 9.15E-6
1200 4.77E-4
1300 1.36E-2
1400 2.39E-1
1500 2.86E0
1600 2.52E1
1700 1.72E2
1800 9.46E2
1900 4.35E3
2000 1.72E4
2100 5.96E4
2200 1.84E5
2300 5.18E5
2400 1.33E6
2500 3.18E6