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Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Tsang, W.; Hampson, R.F.
Title:   Chemical kinetic data base for combustion chemistry. Part I. Methane and related compounds
Journal:   J. Phys. Chem. Ref. Data
Volume:   15
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986TSA/HAM1087

Reaction:   ·C2H5C2H4 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   4.31x1012 [s-1] (T/298 K)1.19 e-155481 [J/mole]/RT
Uncertainty:   2.0
Bath gas:   N2
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 3.69E-15
400 3.04E-8
500 4.56E-4
600 2.89E-1
700 2.98E1
800 9.84E2
900 1.52E4
1000 1.38E5
1100 8.44E5
1200 3.86E6
1300 1.41E7
1400 4.30E7
1500 1.14E8
1600 2.67E8
1700 5.72E8
1800 1.13E9
1900 2.08E9
2000 3.61E9
2100 5.97E9
2200 9.47E9
2300 1.44E10
2400 2.13E10
2500 3.06E10