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Author(s):   Park, J.; Chakraborty, D.; Bhusari, D.M.; Lin, M.C.
Title:   Kinetics of C6H5 radical reactions with toluene and xylenes by cavity ringdown spectrometry
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   4002 - 4008
Year:   1999
Reference type:   Journal article
Squib:   1999PAR/CHA4002-4008

Reaction:   C6D5CD3 + PhenylBenzene-d + C6D5CD2
Reaction order:   2
Temperature:   295 - 483 K
Pressure:  2.32E-2 - 4.00E-2 bar
Rate expression:   3.77x10-13 [±7.14x10-14 cm3/molecule s] e-11141 [±557 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 4.01E-15
300 4.33E-15
325 6.10E-15
350 8.19E-15
375 1.06E-14
400 1.32E-14
425 1.61E-14
450 1.92E-14
475 2.24E-14
483 2.35E-14