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Author(s):   Husain, D.; Sealy, I.P.
Title:   The reaction of ground state lead atoms Pb(63P0), with CH3Cl, C2H5Cl, n-C3H7Cl and SF6 at elevated temperatures by time-resolved atomic resonance absorption spectroscopy
Journal:   J. Photochem.
Volume:   34
Year:   1986
Reference type:   Journal article
Squib:   1986HUS/SEA245

Reaction:   SF6 + PbSF5 + PbF
Reaction order:   2
Temperature:   619 - 812 K
Pressure:  4.51E-2 - 0.20 bar
Rate expression:   7.41x10-10 [±2.99x10-11 cm3/molecule s] e-93122 [±7441 J/mole]/RT
Bath gas:   SF6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
619 1.03E-17
625 1.22E-17
650 2.43E-17
675 4.61E-17
700 8.33E-17
725 1.45E-16
750 2.42E-16
775 3.92E-16
800 6.16E-16
812 7.57E-16