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Title: The reaction of ground state lead atoms Pb(63P0), with CH3Cl, C2H5Cl, n-C3H7Cl and SF6 at elevated temperatures by time-resolved atomic resonance absorption spectroscopy
Journal: J. Photochem.
Volume: 34
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986HUS/SEA245
Reaction:
SF6 + Pb → SF5 + PbF
Reaction order:
2
Temperature:
619 - 812
K
Pressure: 4.51E-2 - 0.20 bar
Rate expression:
7.41x10-10 [±2.99x10-11 cm3/molecule s] e-93122 [±7441 J/mole]/RT
Bath gas:
SF6
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 619 | 1.03E-17 |
| 625 | 1.22E-17 |
| 650 | 2.43E-17 |
| 675 | 4.61E-17 |
| 700 | 8.33E-17 |
| 725 | 1.45E-16 |
| 750 | 2.42E-16 |
| 775 | 3.92E-16 |
| 800 | 6.16E-16 |
| 812 | 7.57E-16 |