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Author(s):   Madden, L.K.; Moskaleva, L.V.; Kristyan, S.; Lin, M.C.
Title:   Ab initio MO study of the unimolecular decomposition of the phenyl radical
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   6790 - 6797
Year:   1997
Reference type:   Journal article
Squib:   1997MAD/MOS6790-6797

Reaction:   Phenyl → Other Products +
Reaction order:   1
Temperature:   700 - 2500 K
Pressure:  1.01 bar
Rate expression:   7.66x1033 [s-1] (T/298 K)-16.00 e-534621 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
700 1.14E-12
800 1.31E-8
900 1.50E-5
1000 3.52E-3
1100 2.65E-1
1200 8.59E0
1300 1.47E2
1400 1.54E3
1500 1.09E4
1600 5.66E4
1700 2.28E5
1800 7.47E5
1900 2.06E6
2000 4.93E6
2100 1.04E7
2200 1.99E7
2300 3.49E7
2400 5.66E7
2500 8.60E7