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Author(s):   Walavalkar, M.P.; Sharma, A.; Dhanya, S.; Naik, P.D.
Title:   Reactions of lactones with tropospheric oxidants: A kinetics and products study
Journal:   Atmos. Environ.
Volume:   161
Page(s):   18 - 26
Year:   2017
Reference type:   Journal article
Squib:   2017WAL/SHA18-26

Reaction:   ·Cl + γ-Valerolactone → Products
Reaction order:   2
Reference reaction:   C2H6 + ·Cl → Products
Temperature:   298 K
Pressure:  1.07 bar
Rate expression:   2.26x10-11 [±5.3x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   The error in the value of the rate constant is calculated by statistically combining the experimental errors and the reported errors in the values the rate constants of the reference reactions.

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