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Author(s):   Atkinson, R.; Aschmann, S.M.; Pitts, J.N., Jr.
Title:   Kinetics of the gas-phase reactions of OH radicals with a series of α,β-unsaturated carbonyls at 299 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   15
Page(s):  
Year:   1983
Reference type:   Journal article
Squib:   1983ATK/ASC75

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1983ATK/ASC75   Methacrolein + ·OH → Products  299   2.86E-11              2
  1983ATK/ASC75   CH2=CHCOCH3 + ·OH → Products  299   1.88E-11              2
  1983ATK/ASC75   CH2=CHCHO + ·OH → Products  299   1.83E-11              2
  1983ATK/ASC75   Cyclohexane + ·OHCyclohexyl + H2O  299   6.79E-12              2
  1983ATK/ASC75   ·OH + (E)-CH3CH=CHCHO → Products  299   3.50E-11              2

Search returned 5 records.