Author(s):   Atkinson, R.; Aschmann, S.M.; Pitts, J.N., Jr.
Title:   Kinetics of the gas-phase reactions of OH radicals with a series of α,β-unsaturated carbonyls at 299 ± 2 K
Journal:   Int. J. Chem. Kinet.
Volume:   15
Page(s):
Year:   1983
Reference type:   Journal article
Squib:   1983ATK/ASC75

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Order
1983ATK/ASC75	Methacrolein + ·OH → Products	299	2.86E-11	2
1983ATK/ASC75	CH₂=CHCOCH₃ + ·OH → Products	299	1.88E-11	2
1983ATK/ASC75	CH₂=CHCHO + ·OH → Products	299	1.83E-11	2
1983ATK/ASC75	Cyclohexane + ·OH → Cyclohexyl + H₂O	299	6.79E-12	2
1983ATK/ASC75	·OH + (E)-CH₃CH=CHCHO → Products	299	3.50E-11	2

Search returned 5 records.