Author(s):   Foon, R.; Tait, K.B.
Title:   Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Page(s):
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/TAI1121

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1972FOO/TAI1121	CCl₄ + ·F → ·CCl₃ + ClF	450 - 470	1.66E-11	4.27E04		2
1972FOO/TAI1121	CFCl₃ + ·F → Products	589 - 733	0.20	-2.08E04		2
Reference reaction: CFCl₂CFCl₂ + ·F → Products					2
1972FOO/TAI1121	CFCl₃ + ·F → ·CCl₂F + ClF	520 - 540	5.25E-12	5.48E04		2
1972FOO/TAI1121	CF₂Cl₂ + ·F → Products	596 - 747	1.09	-6394		2
Reference reaction: CF₂Cl-CF₂Cl + ·F → Products					2
1972FOO/TAI1121	CF₂Cl₂ + ·F → Products	665 - 790	2.63	-6693		2
Reference reaction: CF₃CF₂Cl + ·F → Products					2
1972FOO/TAI1121	CF₂Cl₂ + ·F → ·CClF₂ + ClF	664 - 684	2.62E-11	6.98E04		2
1972FOO/TAI1121	CF₃Cl + ·F → ·CF₃ + ClF	755 - 775	1.05E-10	8.73E04		2
1972FOO/TAI1121	CF₂Cl-CF₂Cl + ·F → ClF + CCl₂F₂CF₂	663 - 683	2.62E-11	7.62E04		2
1972FOO/TAI1121	CF₃CF₂Cl + ·F → C₂F₅ + ClF	725 - 745	1.05E-11	7.70E04		2

Search returned 9 records.