 |
Home ©NIST, 2022 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Reactions des radicaux chlorofluoromethyl peroxyles avec NO: Etude cinetique dans le domaine de temperature compris entre 230 et 430 K
Journal: J. Chim. Phys. Phys. Chim. Biol.
Volume: 82
Page(s):
Year: 1985
Reference type: Journal article
Squib: 1985DOG/CAR349
Reaction:
NO + CClF2OO → NO2 + CF2ClO
Reaction order:
2
Temperature:
230 - 430
K
Pressure: 2.67E-3 - 1.33E-2 bar
Rate expression:
1.6x10-11 [±2.99x10-12 cm3/molecule s] (T/298 K)(-1.50±0.41)
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 230 | 2.36E-11 |
| 250 | 2.08E-11 |
| 275 | 1.81E-11 |
| 300 | 1.58E-11 |
| 325 | 1.41E-11 |
| 350 | 1.26E-11 |
| 375 | 1.13E-11 |
| 400 | 1.03E-11 |
| 425 | 9.40E-12 |
| 430 | 9.24E-12 |