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Title: Kinetics Study of the Reactions of OH with n-Undecane and n-Dodecane Using the RR/DF/MS Technique
Journal: J. Phys. Chem. A
Volume: 121
Page(s): 3647 - 3654
Year: 2017
Reference type: Journal article
Squib: 2017PHA/LI3647-3654
Reaction:
n-C11H24 + ·OH → Other Products + H2O
Reaction order:
2
Temperature:
277 - 340
K
Pressure: 1.33E-3 bar
Rate expression:
6.58x10-12 [±2.6x10-12 cm3/molecule s] e-1979 [±848 J/mole]/RT
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Mass spectrometry
Comments:
n-Decane, n-nonane, n-octane, and n-heptane were used as reference compounds.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 277 | 2.79E-12 |
| 300 | 2.98E-12 |
| 325 | 3.16E-12 |
| 340 | 3.27E-12 |