Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Phan, M.; Li, Z.
Title:   Kinetics Study of the Reactions of OH with n-Undecane and n-Dodecane Using the RR/DF/MS Technique
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   3647 - 3654
Year:   2017
Reference type:   Journal article
Squib:   2017PHA/LI3647-3654

Reaction:   n-C11H24 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   277 - 340 K
Pressure:  1.33E-3 bar
Rate expression:   6.58x10-12 [±2.6x10-12 cm3/molecule s] e-1979 [±848 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   n-Decane, n-nonane, n-octane, and n-heptane were used as reference compounds.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
277 2.79E-12
300 2.98E-12
325 3.16E-12
340 3.27E-12