Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tsang, W.
Title:   Thermal Stability of Primary Amines
Journal:   Int. J. Chem. Kinet.
Volume:   10
Year:   1978
Reference type:   Journal article
Squib:   1978TSA41

Reaction:   tert-C5H11NH2(CH3)2C=CHCH3 + NH3
Reaction order:   1
Temperature:   990 - 1200 K
Rate expression:   3.16x1014 [s-1] e-309298 [J/mole]/RT
Rate constant is an upper limit.
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
990 1.52E-2
1000 2.21E-2
1025 5.47E-2
1050 1.30E-1
1075 2.96E-1
1100 6.50E-1
1125 1.38E0
1150 2.83E0
1175 5.62E0
1200 1.09E1