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Author(s):   Sway, M.I.; Waddington, D.J.
Title:   Reactons of oxygenated radicals in the gas phase. Part 13. Reactions of t-Butoxyl radicals with alkanes and alkenes
Journal:   J. Chem. Soc. Perkin Trans. 2
Year:   1984
Reference type:   Journal article
Squib:   1984SWA/WAD63

Reaction:   iso-C4H10 + (CH3)3CO· → tert-C4H9OH + tert-C4H9
Reaction order:   2
Reference reaction:   (CH3)3CO· → Acetone + ·CH3
Temperature:   399 - 434 K
Pressure:  0.27 - 0.93 bar
Rate expression:   2.29x10-11 [cm3/molecule s] e-23946 [±478 J/mole]/RT
Uncertainty:   1.12
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
399 1.68E-14
400 1.71E-14
425 2.61E-14
434 3.01E-14