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Author(s):   Audley, G.J.; Baulch, D.L.; Campbell, I.M.
Title:   Gas-phase Reactions of Hydroxyl Radicals with Aldehydes in Flowing H2O2 + NO2 + CO Mixtures
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   77
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981AUD/BAU2541

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1981AUD/BAU2541   (CH3)2CHCHO + ·OH → Other Products + H2O  298   1.74E-11           1.74E-11  2
  1981AUD/BAU2541   (CH3)2CHCHO + ·OH → Other Products + H2O  298   1.12           1.12  2
  Reference reaction:  CH3CHO + ·OH → Products 2
  1981AUD/BAU2541   Pentanal + ·OH → Products  298   1.38E-11           1.38E-11  2
  1981AUD/BAU2541   Pentanal + ·OH → Products  298   0.88           0.88  2
  Reference reaction:  CH3CHO + ·OH → Products 2
  1981AUD/BAU2541   C2H5CHO + ·OH → Products  298   1.78E-11           1.78E-11  2
  1981AUD/BAU2541   C2H5CHO + ·OH → Products  298   1.14           1.14  2
  Reference reaction:  CH3CHO + ·OH → Products 2
  1981AUD/BAU2541   CH3CH2CH2CHO + ·OH → Products  298   2.52E-11           2.52E-11  2
  1981AUD/BAU2541   CH3CH2CH2CHO + ·OH → Products  298   1.62           1.62  2
  Reference reaction:  CH3CHO + ·OH → Products 2
  1981AUD/BAU2541   3-Methylbutanal + ·OH → Products  298   1.83E-11           1.83E-11  2
  1981AUD/BAU2541   3-Methylbutanal + ·OH → Products  298   1.18           1.18  2
  Reference reaction:  CH3CHO + ·OH → Products 2
  1981AUD/BAU2541   2,2-dimethylpropanal + ·OH → Products  298   8.49E-12           8.49E-12  2
  1981AUD/BAU2541   2,2-dimethylpropanal + ·OH → Products  298   0.54           0.54  2
  Reference reaction:  CH3CHO + ·OH → Products 2

Search returned 12 records.