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Author(s):   Wallington, T.J.; Potts, A.R.; Andino, J.M.; Siegl, W.O.; Zhang, Z.; Kurylo, M.J.; Huie, R.E.
Title:   Kinetics of the reaction of OH radicals with t-amyl methyl ether revisited
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   265 - 272
Year:   1993
Reference type:   Journal article
Squib:   1993WAL/POT265-272

Reaction:   C2H5C(CH3)2OCH3 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   240 - 400 K
Pressure:  4.71E-2 bar
Rate expression:   6.31x10-12 [±6.97x10-13 cm3/molecule s] e-333 [±582 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
240 5.34E-12
250 5.38E-12
275 5.46E-12
300 5.52E-12
325 5.58E-12
350 5.63E-12
375 5.67E-12
400 5.71E-12