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Accessibility information
Author(s):   Teton, S.; Mellouki, A.; LeBras, G.; Sidebottom, H.
Title:   Rate constants for reactions of OH radicals with a series of asymmetrical ethers and tert-butyl alcohol
Journal:   Int. J. Chem. Kinet.
Volume:   28
Page(s):   291 - 297
Year:   1995
Reference type:   Journal article
Squib:   1995TET/MEL291-297

Reaction:   C2H5C(CH3)2OCH3 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   231 - 372 K
Pressure:  0.13 bar
Rate expression:   6.73x10-13 [±4.65x10-14 cm3/molecule s] (T/298 K)2.00 e5454 [±382 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
231 6.92E-12
250 6.53E-12
275 6.22E-12
300 6.07E-12
325 6.02E-12
350 6.05E-12
372 6.11E-12