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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Reactions of trifluoromethyl radicals with iodine and hydrogen iodide
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):  
Year:   1967
Reference type:   Journal article
Squib:   1967AMP/WHI2695

Reaction:   CF3Br + Br· → ·CF3 + Br2
Reaction order:   2
Temperature:   350 - 600 K
Rate expression:   1.08x10-10 [cm3/molecule s] e-101437 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
350 7.85E-26
375 8.02E-25
400 6.13E-24
425 3.68E-23
450 1.82E-22
475 7.56E-22
500 2.73E-21
525 8.73E-21
550 2.51E-20
575 6.59E-20
600 1.59E-19