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Accessibility information
Author(s):   Amphlett, J.C.; Whittle, E.
Title:   Bromination of fluoroalkanes. Part 4.-Kinetics of thermal bromination of fluoroform and pentafluorethane
Journal:   Trans. Faraday Soc.
Volume:   64
Year:   1968
Reference type:   Journal article
Squib:   1968AMP/WHI2130

Reaction:   CF3Br + Br··CF3 + Br2
Reaction order:   2
Temperature:   350 - 600 K
Rate expression:   1.05x10-10 [cm3/molecule s] e-101437 [±8132 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   CF3Br
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
350 7.62E-26
375 7.78E-25
400 5.95E-24
425 3.58E-23
450 1.76E-22
475 7.34E-22
500 2.65E-21
525 8.47E-21
550 2.44E-20
575 6.39E-20
600 1.55E-19