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Title: Kinetics of the reaction between HBr and CF3Br. Determination of the bond dissociation energy D(CF3-Br)
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 68
Page(s):
Year: 1972
Reference type: Journal article
Squib: 1972FER/WHI295
Reaction:
CF3Br + Br· → ·CF3 + Br2
Reaction order:
2
Temperature:
641 - 810
K
Pressure: 0.70 - 0.92 bar
Rate expression:
1.35x10-10 [cm3/molecule s] e-105594 [±1056 J/mole]/RT
Uncertainty:
1.32000005
Bath gas:
HBr
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 641 | 3.36E-19 |
| 650 | 4.41E-19 |
| 675 | 9.10E-19 |
| 700 | 1.78E-18 |
| 725 | 3.33E-18 |
| 750 | 5.97E-18 |
| 775 | 1.03E-17 |
| 800 | 1.72E-17 |
| 810 | 2.09E-17 |