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Accessibility information
Author(s):   Ferguson, K.C.; Whittle, E.
Title:   Kinetics of the reaction between HBr and CF3Br. Determination of the bond dissociation energy D(CF3-Br)
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FER/WHI295

Reaction:   CF3Br + Br··CF3 + Br2
Reaction order:   2
Temperature:   641 - 810 K
Pressure:  0.70 - 0.92 bar
Rate expression:   1.35x10-10 [cm3/molecule s] e-105594 [±1056 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   HBr
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
641 3.36E-19
650 4.41E-19
675 9.10E-19
700 1.78E-18
725 3.33E-18
750 5.97E-18
775 1.03E-17
800 1.72E-17
810 2.09E-17