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Accessibility information
Author(s):   Ferguson, K.C.; Whittle, E.
Title:   Competitive study of the reactions Br+RBr→’Br2+R(R = CF3, C2F5)
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FER/WHI641

Reaction:   CF3Br + Br··CF3 + Br2
Reaction order:   2
Reference reaction:   C2F5Br + Br·C2F5 + Br2
Reference reaction order:   2
Temperature:   468 - 749 K
Pressure:  0.28 - 1.33 bar
Rate expression:   1.84 e-9728 [±873 J/mole]/RT
Uncertainty:   1.19000006
Bath gas:   HBr
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
468 1.51E-1
475 1.57E-1
500 1.77E-1
525 1.98E-1
550 2.19E-1
575 2.41E-1
600 2.62E-1
625 2.83E-1
650 3.04E-1
675 3.25E-1
700 3.46E-1
725 3.66E-1
749 3.86E-1