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Accessibility information
Author(s):   Gangloff, H.J.; Milks, D.; Maloney, K.L.; Adams, T.N.; Matula, R.A.
Title:   An experimental and mechanistic study of the reactions of COF2 with H2 and with CO
Journal:   J. Chem. Phys.
Volume:   63
Page(s):   4915 - 4926
Year:   1975
Reference type:   Journal article
Squib:   1975GAN/MIL4915-4926

Reaction:   FCOCO + ·F
Reaction order:   2
Temperature:   2600 - 3300 K
Pressure:  2.53 - 9.12 bar
Rate expression:   1.66x10-9 [cm3/molecule s] e-205367 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
2600 1.24E-13
2650 1.49E-13
2700 1.77E-13
2750 2.09E-13
2800 2.45E-13
2850 2.86E-13
2900 3.32E-13
2950 3.84E-13
3000 4.41E-13
3050 5.05E-13
3100 5.75E-13
3150 6.53E-13
3200 7.38E-13
3250 8.31E-13
3300 9.32E-13