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Accessibility information
Author(s):   Sun, W.; Tao, T.; Zhang, R.; Liao, H.; Huang, C.; Zhang, F.; Zhang, X.; Zhang, Y.; Yang, B.
Title:   Experimental and modeling efforts towards a better understanding of the high-temperature combustion kinetics of C-3-C-5 ethyl esters
Journal:   Combust. Flame
Volume:   185
Page(s):   173 - 187
Year:   2017
Reference type:   Journal article
Squib:   2017SUN/TAO173-187

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2017SUN/TAO173-187   HC(O)OC2H5HCOOH + C2H4  500 - 2000   7.85E16   -4.63   2.40E05      1
  2017SUN/TAO173-187   HC(O)OC2H5C2H5OH + CO  500 - 2000   3.68E21   -9.01   3.37E05      1
  2017SUN/TAO173-187   CH3C(O)OC2H5CH3C(O)OH + C2H4  500 - 2000   2.41E16   -4.09   2.29E05      1
  2017SUN/TAO173-187   CH3C(O)OC2H5·CH3 + CH3C(O)OCH2·  500 - 2000   1.79E28   -13.73   4.48E05      1
  2017SUN/TAO173-187   HC(O)OC2H5·CH3 + HC(O)OCH2(·)  500 - 2000   5.50E27   -14.46   4.48E05      1
  2017SUN/TAO173-187   CH3C(O)OC2H5·C2H5 + CH3C(O)O  500 - 2000   1.11E29   -14.21   4.56E05      1
  2017SUN/TAO173-187   CH3C(O)OC2H5·CH3 + CH3CH2OC(O)·  500 - 2000   5.08E27   -14.46   4.64E05      1
  2017SUN/TAO173-187   CH3C(O)OC2H5C2H5OH + H2C=C=O  500 - 2000   1.00E19   -7.23   3.42E05      1
  2017SUN/TAO173-187   CH3C(O)OC2H5 → CH2=C(OH)OC2H5  500 - 2000   2.50E17   -6.30   3.17E05      1
  2017SUN/TAO173-187   CH2=C(OH)OC2H5C2H5OH + H2C=C=O  500 - 2000   5.40E16   -5.00   1.99E05      1
  2017SUN/TAO173-187   HC(O)OC2H5 → ·OC(O)H + ·C2H5  500 - 2000   1.20E28   -14.73   4.56E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5 → ·H2CC(O)OCH2CH3 + ·CH3  500 - 2000   4.01E25   -10.76   4.23E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5 → CH3CH2C(O)OCH2· + ·CH3  500 - 2000   4.84E26   -11.57   4.44E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5·C2H5 + CH3CH2C(O)O·  500 - 2000   8.52E26   -11.48   4.39E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5·C2H5 + CH3CH2OC(O)·  500 - 2000   2.27E27   -12.30   4.56E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5CH3CH2 + CH3CH2CO  500 - 2000   1.61E28   -13.90   4.90E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5C2H5OH + CH3CH=C=O  500 - 2000   2.22E19   -6.82   3.54E05      1
  2017SUN/TAO173-187   C2H5C(O)OC2H5 → CH3CH=C(OH)OC2H5  500 - 2000   9.17E17   -6.64   3.29E05      1
  2017SUN/TAO173-187   CH3CH=C(OH)OC2H5C2H5OH + CH3CH=C=O  500 - 2000   3.30E15   -3.78   1.90E05      1

Search returned 19 records.