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Title: Der thermische zerfall von chlorierten athylenen in der gasphase. I. Tetrachlorathylen und trichlorathylen
Journal: Ber. Bunsenges. Phys. Chem.
Volume: 78
Page(s):
Year: 1974
Reference type: Journal article
Squib: 1974ZAB232
Reaction:
C2HCl3 → Products
Reaction order:
1
Temperature:
1450 - 1900
K
Pressure: 2.03 - 177 bar
Rate expression:
7.0x1015 [s-1] e-351702 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1450 | 1.50E3 |
| 1475 | 2.46E3 |
| 1500 | 3.96E3 |
| 1525 | 6.29E3 |
| 1550 | 9.84E3 |
| 1575 | 1.52E4 |
| 1600 | 2.31E4 |
| 1625 | 3.47E4 |
| 1650 | 5.14E4 |
| 1675 | 7.54E4 |
| 1700 | 1.09E5 |
| 1725 | 1.57E5 |
| 1750 | 2.23E5 |
| 1775 | 3.13E5 |
| 1800 | 4.36E5 |
| 1825 | 6.01E5 |
| 1850 | 8.22E5 |
| 1875 | 1.12E6 |
| 1900 | 1.50E6 |