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Author(s):   Zabel, V.F.
Title:   Der thermische zerfall von chlorierten athylenen in der gasphase. I. Tetrachlorathylen und trichlorathylen
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   78
Year:   1974
Reference type:   Journal article
Squib:   1974ZAB232

Reaction:   C2HCl3 → Products
Reaction order:   2
Temperature:   1450 - 1900 K
Pressure:  2.03 - 177 bar
Rate expression:   2.32x10-7 [cm3/molecule s] e-244445 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1450 3.64E-16
1475 5.13E-16
1500 7.15E-16
1525 9.86E-16
1550 1.35E-15
1575 1.82E-15
1600 2.43E-15
1625 3.23E-15
1650 4.25E-15
1675 5.54E-15
1700 7.17E-15
1725 9.21E-15
1750 1.18E-14
1775 1.49E-14
1800 1.87E-14
1825 2.34E-14
1850 2.91E-14
1875 3.60E-14
1900 4.43E-14