 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Der Thermische Zerfall von Chlorierten Athylenen in der Gasphase I. Tetrachloroathylen und Trichloroathylen
Journal: Ber. Bunsenges. Phys. Chem.
Page(s): 232 - 240
Year: 1977
Reference type: Journal article
Squib: 1977ZAB232-240
Reaction:
C2HCl3 → Products
Reaction order:
2
Temperature:
1450 - 1900
K
Pressure: 2.03 - 177 bar
Rate expression:
2.32x10-7 [cm3/molecule s] e-244764 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is low pressure limit
Experimental procedure:
Other
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
Shock tube measurement.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1450 | 3.54E-16 |
| 1475 | 5.00E-16 |
| 1500 | 6.97E-16 |
| 1525 | 9.61E-16 |
| 1550 | 1.31E-15 |
| 1575 | 1.77E-15 |
| 1600 | 2.38E-15 |
| 1625 | 3.15E-15 |
| 1650 | 4.15E-15 |
| 1675 | 5.42E-15 |
| 1700 | 7.01E-15 |
| 1725 | 9.01E-15 |
| 1750 | 1.15E-14 |
| 1775 | 1.46E-14 |
| 1800 | 1.84E-14 |
| 1825 | 2.30E-14 |
| 1850 | 2.86E-14 |
| 1875 | 3.53E-14 |
| 1900 | 4.34E-14 |