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Author(s):   Zabel, V.F.
Title:   Der Thermische Zerfall von Chlorierten Athylenen in der Gasphase I. Tetrachloroathylen und Trichloroathylen
Journal:   Ber. Bunsenges. Phys. Chem.
Page(s):   232 - 240
Year:   1977
Reference type:   Journal article
Squib:   1977ZAB232-240

Reaction:   C2HCl3 → Products
Reaction order:   1
Temperature:   1450 - 1900 K
Pressure:  2.03 - 177 bar
Rate expression:   7.0x1015 [s-1] e-351456 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Other
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Shock tube measurement.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1450 1.53E3
1475 2.51E3
1500 4.04E3
1525 6.42E3
1550 1.00E4
1575 1.55E4
1600 2.35E4
1625 3.53E4
1650 5.24E4
1675 7.68E4
1700 1.11E5
1725 1.60E5
1750 2.26E5
1775 3.18E5
1800 4.43E5
1825 6.11E5
1850 8.36E5
1875 1.13E6
1900 1.52E6