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Author(s):   Cadman, P.; Owen, H.L.
Title:   Abstraction of chlorine and bromine atoms from alkyl halides by the trifluorosiyl radical
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   77
Year:   1981
Reference type:   Journal article
Squib:   1981CAD/OWE1913

Reaction:   iso-C3H7Cl + SiF32-C3H7 + SiClF3
Reaction order:   2
Reference reaction:   1-C4H9Cl + SiF31-C4H9 + SiClF3
Reference reaction order:   2
Temperature:   475 - 565 K
Pressure:  1.01 bar
Rate expression:   1.11±2.3x10-1 e7408 [±890 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
475 7.24E0
500 6.60E0
525 6.06E0
550 5.61E0
565 5.37E0