Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2020 Accessibility information |
Title: Kinetics and mechanisms of gas-phase elimination of 2,2-diethoxyethyl amine and 2,2-diethoxy-N,N-diethylethanamine
Journal: J. Phys. Org. Chem.
Volume: 21
Page(s): 359 - 364
Year: 2008
Reference type: Journal article
Squib: 2008MOR/DOM359-364
Reaction:
Diethylaminoacetaldehyde diethyl acetal → C2H5OCH=CHN(C2H5)2 + C2H5OH
Reaction order:
1
Temperature:
593 - 653
K
Pressure: 5.33E-2 - 0.20 bar
Rate expression:
8.7x1013 [±5.0x1013 s-1] e-202300 [±2400 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 593 | 1.32E-4 |
| 600 | 2.13E-4 |
| 625 | 1.08E-3 |
| 650 | 4.82E-3 |
| 653 | 5.72E-3 |