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Author(s):   Wojcik-Pastuszka, D.; Jodkowski, J.T.
Title:   Spectrokinetic Study of the Reaction System of 2NO 2<-> N2O4 with Butanols Between 320-358 K in the Gas Phase
Journal:   Pol. J. Chem.
Volume:   83
Page(s):   131 - 143
Year:   2009
Reference type:   Journal article
Squib:   2009WOJ/JOD131-143

Reaction:   n-C4H9OH + N2O4n-C4H9ONO + HNO3
Reaction order:   2
Temperature:   298 K
Pressure:  0.25 - 0.50 bar
Rate expression:   3.9x10-18 [±1.0x10-18 cm3/molecule s]
Category:  Experiment
Data type:   Estimated: thermochemical, kinetic, or other
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Reaction was studied in the 320 - 358 K temperature range. The value of the rate constant reported here is an extrapolation to 298 K reported by the authors.

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