Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Low-Temperature Synchrotron Photoionization Study of 2-Methyl-3-buten-2-ol (MBO) Oxidation Initiated by O(P-3) Atoms in the 298-650 K Range
Journal: J. Phys. Chem. A
Volume: 121
Page(s): 2936 - 2950
Year: 2017
Reference type: Journal article
Squib: 2017FAT/PRI2936-2950
Reaction:
CH2=CHC(CH3)2OH + O· → Other Products + CH3CHO
Reaction order:
2
Reference reaction:
CH2=CHC(CH3)2OH + O· → Products
Reference reaction order:
2
Temperature:
298
K
Pressure: 5.33E-3 bar
Rate expression:
4.2x10-2±1.5x10-2
Category: Experiment
Data type:
Relative rate value measured
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Mass spectrometry
Comments:
Experiments were performed at temperatures 298 - 650 K and pressures of 4 - 7 Torr. At elevated temperatures, other products were observed. Branching fractions at individual temperatures are presented in a tabular format. No Arrhenius expressions are given, The quoted values are for the room temperature.
View full bibliographic record.